Activated carbon produced from coconut shells and optimized for MTBE adsorption may reduce MTBE to undetectable levels,[26] although this level of reduction is likely to occur only in the most ideal circumstances. It is also unstable toward strong acids. [13] Worldwide production capacity of MTBE in 2018 was estimated to be 35 million metric tons.[14]. 600059 ; 99 atom % 13 C; Sigma-Aldrich pricing SDS. Methyl tert-butyl ether (MTBE) has been phased out from the gasoline pool in many countries because of its water solubility, which brings about significant pollution in lakes and underground water sources (Ahmed, 2001). Hahn H et al; Butanols. Learn more about tert-Butyl methyl ether. 62K1064 – you will only find the COO if Er hat zum einen wegen seiner Verwendung als Zusatzstoff in Ottokraftstoffen sowie zum anderen als Lösungsmittel in der organischen Chemie eine gewisse großtechnische Bedeutung erlangt. In the U.S. MTBE has been used in gasoline at low levels since 1979, replacing tetraethyllead (TEL) as an antiknock (octane rating) additive to prevent engine knocking. MTBE is biodegraded by the action of bacteria. MTBE, MTB, 2-Methoxy-2-methylpropane, Methyl tert-butyl ether, tert-Butyl methyl ether Puriss. Exposure may occur by breathing air contaminated with auto exhaust or gasoline fumes while refueling autos. Sigma-Aldrich offers a number of tert -Butyl methyl ether products. Ullmann's Encyclopedia of Industrial Chemistry 7th ed. Ethanol has been advertised as a safe alternative by agricultural and other interest groups in the U.S. and Europe. methyl tert-butyl ether that will exceed production for some time to come (Scholz et al., 1990). In the article it is stated at its first paragraph that (quote) Methyl tert-butyl ether, also known as methyl tertiary butyl ether and MTBE, is a chemical compound with molecular formula C5H12O. tert-Butyl methyl ether for synthesis. The reaction for making tert-Butyl methyl ether proceeds quickly and highly selectively by reacting a mixed butene-butane fraction with methyl alcohol in the liquid phase on a fixed bed of an acidic ion-exchange resin catalyst. Its performance as an additive is similar to MTBE, but due to the higher price of ethanol compared to methanol, it is more expensive. Chemsrc provides Methyl tert-butyl ether(CAS#:1634-04-4) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others. [2][3], MTBE is manufactured via the chemical reaction of methanol and isobutylene. - Find MSDS or SDS, a COA, data sheets and more information. Pressure-Temperature Calculator for Solvents, Solvents for Liquid Chromatography LiChrosolv®. [7], MTBE production in the U.S. peaked in 1999 at 260,000 barrels per day[8] before dropping down to about 50,000 barrels per day and holding steady,[9] mostly for the export market. Other solubilities: miscible with most organic solvents, unstable in acid solutions, soly of water in methyl-t-butyl ether : 1,5g/100g SMILES Solubility : 4.8 g/100g of water. Site Use Terms [30] However, MTBE is still legal in the state for other industrial uses.[31]. [6] Isobutylene can be produced through a variety of methods. Methyl tert-butyl Ether (1634- 04 -4) No No 3 12. Methyl tert-butyl ether (MTBE), also known as tert-butyl methyl ether, is an organic compound with a structural formula (CH3)3COCH3. [5] The resulting gases then further react in the presence of a catalyst to form methanol. STBB0728K9 - enter the lot number STBB0728 without the filling-code Before the introduction of other oxygenates and octane enhancers, refiners chose MTBE for its blending characteristics and low cost. Primarily used as a fuel additive, MTBE is blended into gasoline to increase knock resistance and reduce unwanted emissions. Solubility in water: 51g/L (20°C). MTBE is used as a fuel component in fuel for gasoline engines. EC-No. Methyl tert-butyl ether (also known as MTBE and tert-butyl methyl ether) is an organic compound with a structural formula (CH 3) 3 COCH 3.MTBE is a volatile, flammable, and colorless liquid that is sparingly soluble in water. Did you use this product in your Paper? [15][16], MTBE is extensively used in industry as a safer alternative to diethyl ether (which is commonly used in academic research) as the tert-butyl group prevents MTBE from forming potentially explosive peroxides. INTRODUCTION Methyl tert-butyl ether (MTBE) is a fuel oxygenate commonly added to gasoline at 11-15% concentration to improve fuel … ... Solubility. 1634-04-4 - BZLVMXJERCGZMT-UHFFFAOYSA-N - t-Butyl methyl ether - Similar structures search, synonyms, formulas, resource links, and other chemical information. - Find MSDS or SDS, a COA, data sheets and more information. Methyl tert-butyl ether (MTBE), also known as tert-butyl methyl ether, is an organic compound with a structural formula (CH 3) 3 COCH 3. The water solubility and biodegradation of the gasoline additive MTBE (methyl-tert.-butyl-ether) were studied in laboratory batch experiments. K9. (1999-2013). 1 Product Result | Match Criteria: Product Name Linear Formula: (13 CH 3) 3 13 CO 13 CH 3. [28], In 2000, EPA drafted plans to phase out the use of MTBE nationwide over four years. Solubility of Anthracene in Ternary Methyl tert-Butyl Ether + Alcohol + 2,2,4-Trimethylpentane Solvent Mixtures at 298.15 K Karen J. Pribyla, Christopher Ezell, Tiffany T. Van, and William E. Acree, Jr.* Department of Chemistry, University of North Texas, Denton, Texas 76203-5070 Healthy male volunteers were exposed via inhalation to gasoline oxygenates methyl tert-butyl ether or tert-amyl methyl ether (TAME).The 4-hr exposures were carried out in a dynamic chamber at 25 and 75 ppm for MTBE and at 15 and 50 ppm for TAME. : 1634 -04 -4 Molecular Weight : 88.15 Chemical Formula : C5H12O CH 3 OH + (CH 3) 2 C=CH 2 → CH 3 OC(CH 3) 3 Reactor effluent is distilled, giving tert-Butyl methyl ether of 99% purity. Primarily used as a fuel additive, MTBE is blended into gasoline to increase knock resistance and reduce unwanted emissions. United States. Concentration tert-Butyl methyl ether 1634-04-4 216-653-1 603-181-00-X - 4. Sigma-Aldrich Products are sold exclusively through Sigma-Aldrich, Inc. Primarily used as a fuel additive, MTBE is blended into gasoline to increase knock resistance and reduce unwanted emissions. CAS 1634-04-4, EC Number 216-653-1, chemical formula (CH₃)₃COCH₃. There are currently no known published cases of any in-situ treatment method that has been capable of reducing contaminant concentrations to baseline (pre-development) conditions within the aquifer soil matrix. The solubility of MTBE in water in equilibrium with a model gasoline mixture with an initial concentration of MTBE of 6.3 % (w/w) was about 900 mg/l. If you find a lot number with a filling-code such as Reference substance name: tert-butyl methyl ether EC Number: 216-653-1 EC Name: tert-butyl methyl ether CAS Number: 1634-04-4 Molecular formula: C5H12O All Rights Reserved. MTBE started to be used in gasoline in the early 1980s as a substitute for tetraethyl lead as an anti-knocking agent [19].It provided oxygen to the combustion reaction, thereby reducing exhaust emissions, although the impact of this is negligible with today's modern engines. Energy Policy Act of 2005. MTBE may be tasted in water at concentrations of 5 – 15 µg/l. [32] This bill did include a provision that gave MTBE makers, including some major oil companies, $2 billion in transition assistance while MTBE was phased out over the following nine years. Methyl tert-Butyl Ether. 600059 ; 99 atom % 13 C; Sigma-Aldrich pricing SDS. Solubility in water: 51g/L (20°C). tert-Butyl methyl ether, Purity (GC): ≥ 99.8 %Identity (IR): conformsEvaporation residue: ≤ 2.0 mg/lWater: ≤ 0.02 %Acidity: ≤ 0.0002 meq/gAlkalinity: ≤ 0.0002 meq/gTransmission (at 240 nm): ≥ 60 %Transmission (at 255 nm): ≥ 85 %Transmission (from 280 nm): ≥ 98 %Filtered by 0.2 µm filter, LICHROSOLV is a registered trademark of Merck KGaA, Darmstadt, Germany. CAD - Chemical Agents Directive, Art. The higher water solubility and persistence of MTBE cause it to travel faster and farther than many other components of gasoline when released into an aquifer.[25]. It is one of a group of chemicals commonly known as oxygenates because they raise the oxygen content of gasoline. State of New York. California banned MTBE as a gasoline additive in 2002. Other solubilities: miscible with most organic solvents, unstable in acid solutions, soly of water in methyl-t-butyl ether : 1,5g/100g Water Customer Service, Synonym: If you find a lot number with a filling-code such as Lot and Batch Numbers can be found on a product's label Page 1 of 8 MSD S: METHLY TERT-BUTYL ETHER MATERIAL SAFETY DATA SHEET- (MSDS) METHYL TERT-BUTYL ETHER 1. (1,4,5) Methyl tert-butyl ether occurs as a colorless liquid, with a vapor pressure of 245 mm Hg at 25 °C. CAS Number: 1173021-74-3. Solubility Potency. Assessment of the Mutagenicity of Methyl Tertiary Butyl Ether at thehprtGene in CD-1 Mice. presented with a COA Request form. M.R. Other solubilities: miscible with most organic solvents, unstable in acid solutions, soly of water in methyl-t-butyl ether : 1,5g/100g Specific Gravity The overall mean pulmonary retention of MTBE was 43 +/- 2.6%; the corresponding mean for TAME was 51 +/- 3.9%. "Announcement of the Drinking Water Contaminant Candidate List. Alternative oxygenates to MTBE, namely ethyl tert-butyl ether (ETBE), tert-amyl ether (TAME) and diisopropyl ether (DIPE) have been hardly studied yet. 40477 tert-Butyl methyl ether, HPLC Grade, 99+% CAS Number. MTBE started to be used in gasoline in the early 1980s as a substitute for tetraethyl lead as an anti-knocking agent [19].It provided oxygen to the combustion reaction, thereby reducing exhaust emissions, although the impact of this is negligible with today's modern engines. If so click here. tert-Butyl methyl ether-13 C 5. Methyl tert-butyl ether (MTBE) has been phased out from the gasoline pool in many countries because of its water solubility, which brings about significant pollution … Methyl tert-butyl ether (also known as MTBE and tert-butyl methyl ether) is an organic compound with a structural formula (CH 3) 3 COCH 3. Articles of Methyl tert-butyl ether are included as well. [citation needed], EPA first listed MTBE in 1998 as a candidate for development of a national Maximum Contaminant Level (MCL) standard in drinking water. Structure, properties, spectra, suppliers and links for: tert-Butyl ethyl ether, 637-92-3. Methanol is a derived from natural gas, and isobutylene is made from crude oil or natural gas, thus MTBE, as used in motor gasoline, is a fossil fuel. It is slightly soluble in water and very soluble ethers and alcohol and in most organic solvents including hydro carbons. [29] The State of New York banned the use of MTBE as a "fuel additive", effective in 2004. In humans, clearance by exhalation is slower in comparison to rats. MTBE (nach IUPAC-Nomenklatur: 2-Methoxy-2-methylpropan, ausgeschrieben auch Methyl-tert-butylether) ist eine organisch-chemische Verbindung aus der Stoffgruppe der aliphatischen Ether. From Wikipedia. tert-Butyl methyl ether for liquid chromatography LiChrosolv ® Synonym: MTBE, MTB, 2-Methoxy-2-methylpropane, Methyl tert-butyl ether, tert-Butyl methyl ether CAS Number 1634-04-4. following the words 'Lot' or 'Batch'. tert-Butyl methyl ether-d 12. Charles Babington, House Again Passes GOP Energy Measures, Washington Post, June 16, 2004, at A4 (House passes Energy Bill, but Senate opponents of MTBE provision in House Bill have the votes to prevent its enactment). [41] As of 2020 the agency has not announced whether it will develop an MCL. An ether having methyl and tert-butyl as the two alkyl components. In the proper type of bioreactor, such as a fluidized bed bioreactor, MTBE may be removed rapidly and economically from water to undetectable levels. MTBE started to be used in gasoline in the early 1980s as a substitute for tetraethyl lead as an anti-knocking agent [19].It provided oxygen to the combustion reaction, thereby reducing exhaust emissions, although the impact of this is negligible with today's modern engines. It reacts dangerously with bromine. 31, 334-337. According to the IARC, a cancer research agency of the World Health Organization, MTBE is not classified as a human carcinogen. We enable science by offering product choice, services, process excellence and our people make it happen. in front of the letter e.g. FIRST AID MEASURES General advice Consult a physician. Questions? Type in Product Names, Product Numbers, or CAS Numbers to see suggestions. LiChrosolv® solvents are designed to optimally support analytical HPLC, fast chromatography, a...Keywords: Chromatography, Evaporation, High performance liquid chromatography, Liquid chromatography mass spectrometry, Mass spectrometry, Phase transitions, Separation, Solvents. tert-Butyl methyl ether for spectroscopy Uvasol®. -021. Methyl tertiary-butyl ether (MTBE) is a chemical compound with molecular formula C 5 H 12 O. MTBE is a volatile, flammable and colorless liquid that is immiscible, yet reasonably soluble in water. Three studies of short-term toxicity to higher plants are available: unfortunately two monitored seed germination and post-emergence growth over only 5 days, much shorter than the relevant OECD test guideline requires and neither study is considered reliable for use in assessment. Show More. Methyl tert-butyl ether (also known as MTBE and tert-butyl methyl ether) is an organic compound with a structural formula (CH3)3COCH3. Tang G, Wang J, Zhuang Z (1997). The Energy Policy Act of 2005, as approved by the U.S. House of Representatives, did not include a provision for shielding MTBE manufacturers from water contamination lawsuits. [44], Except where otherwise noted, data are given for materials in their, Alternatives to MTBE as an anti-knock agent, Persistence and pervasiveness in the environment, Restrictions on MTBE manufacturing and use. Information regarding the chemical MTBE plants can be retrofitted to produce iso-octane from isobutylene. Methyl tert-Butyl Ether. Methyl tert-butyl ether, MTB, MTBE: Description: tert-Butyl methyl ether: Overview: EMSURE® grade solvents are suitable for a broad spectrum of classical lab applications, and are frequently used in regulated and highly demanding lab applications. After the purchase of SABIC,[10][11] oil giant Saudi Aramco is now considered to be the world's largest producer[12] with an estimated production capacity of 2.37 million metric tons per year (mt/yr). Antoine's Coefficients were obtained from the National Institute of Standards an... For perfect high-performance liquid chromatography (HPLC) results, high-performance solvents are a must. © 2021  Merck KGaA, Darmstadt, Germany and/or its affiliates. ", United States Environmental Protection Agency, Institute for Occupational Safety and Health, "Methyl tertiary butyl ether prices, markets & analysis", "Hydrogen production via natural gas steam reforming in a Pd-Au membrane reactor. [40], As of 2016, hundreds of lawsuits are still pending regarding MTBE contamination of public and private drinking water supplies. tert-butyl methyl ether; MTBE; 2-methoxy-2-methylpropane . METHYL TERT-BUTYL ETHER: ICSC: 1164: tert-Butyl methyl ether MTBE Methyl-1,1-dimethylethyl ether 2-Methoxy-2-methyl propane: November 2000 you enter 062K1064. 1634-04-4. [43], California established a state-level MCL for MTBE, 13 micrograms per liter, in 2000. ", http://www.cnn.com/2005/POLITICS/04/21/energy.bill.mtbe.ap/, "House approves $12 billion energy package", "Long Island Utility Fighting to Defeat MTBE Safe Harbor", "Oil Companies Pay Santa Monica MTBE Cleanup Costs", "City Awarded $105 Million in Exxon Mobil Lawsuit", "Exxon Mobil is Found Negligent in New Hampshire MTBE Use", "Drinking Water Regulations Under Development or Review", "How EPA Regulates Drinking Water Contaminants", "MTBE: Regulations and Drinking Water Monitoring Results", https://en.wikipedia.org/w/index.php?title=Methyl_tert-butyl_ether&oldid=1001798315, Pages using collapsible list with both background and text-align in titlestyle, Articles containing unverified chemical infoboxes, Articles with unsourced statements from April 2018, Creative Commons Attribution-ShareAlike License, This page was last edited on 21 January 2021, at 11:25. If your [citation needed] Some states enacted MTBE prohibitions without waiting for federal restrictions. Other solubilities: miscible with most organic solvents, unstable in acid solutions, soly of water in methyl-t-butyl ether : 1,5g/100g Water [35] The lack of MTBE liability protection is resulting in a switchover to the use of ethanol as a gasoline additive. | Privacy. The United States Environmental Protection Agency (EPA) has concluded that available data are inadequate to quantify health risks of MTBE at low exposure levels in drinking water, but the data support the conclusion that MTBE is a potential human carcinogen at high doses. Although an ether, MTBE is a poor Lewis base and does not support formation of Grignard reagents. Grade Specifications. Other oxygenates are available as additives for gasoline including ethanol and other ethers such as ETBE. number 09019TO without the first two letters. Add Spectra . [27], As of 2007, researchers have limited data about the health effects of ingestion of MTBE. It also is used as a solvent in academic research,[17][18][19] although it is used less commonly than diethyl ether. This monograph for Methyl tert-Butyl Ether provides, in addition to common physical constants, a general description including typical appearance, applications, change in state (approximate), aqueous solubility, and density. It is also used in significant quantities in China and Japan (Miller, 1998). Synonyms Methyl tert-butyl ether. Vroeger werd daarvoor het giftige tetraethyllood (TEL) gebruikt (loodhoudende benzine). Methanol is primarily derived from natural gas,[4] where steam reforming converts the various light hydrocarbons in natural gas (primarily methane) into carbon monoxide and hydrogen. tert-Butyl methyl ether-d 12. Methyl tertiary butyl ether; prohibited. CAS 1634-04-4, EC Number 216-653-1, chemical formula (CH₃)₃COCH₃. Contact Maximum level of impurities: Evaporation residue 2ppm, H 2 O 0.05%. Methyl tert-butyl ether, MTB, MTBE: Description: tert-Butyl methyl ether: Overview: EMSURE® grade solvents are suitable for a broad spectrum of classical lab applications, and are frequently used in regulated and highly demanding lab applications. Structure, properties, spectra, suppliers and links for: Methyl tert-butyl ether, 1634-04-4, (CH3)3COCH3. Structure, properties, spectra, suppliers and links for: tert-Butyl ethyl ether, 637-92-3. MTBE (Methyl-tert-Butyl Ether) is a volatile, low viscosity clear liquid at room temperature with an ether odour; boiling point 55.2 C; melting point -109 C. MTBE is flammable and can form explosive mixtures with air. Zhonghua Yu Fang Yi Xue Za Zhi. tert-Butyl methyl ether-13 C 5. ChEBI CHEBI:27642: An ether having methyl and tert-butyl as the two alkyl components. Similarly, the methyl tert-butyl ether synthesis with slight traces of water in the feedstock (methanol and C4-olefins) produces 2-methyl-2-propanol as a byproduct. Reproduction of any materials from the site is strictly forbidden without permission. Product Identification Synonyms : 2-Methoxy-2-methylpropane; tert-Butyl methyl ether; Methyl 1,1-dimethyl ethyl ether; MTBE CAS No. In 2003, California was the first U.S. state to start replacing MTBE with ethanol. An alternative to ethanol is ETBE, which is manufactured from ethanol and isobutene. MTBE is a volatile, flammable, and colorless liquid that is sparingly soluble[1] in water. [22], In a medical procedure called contact dissolution therapy, MTBE is injected directly into the gallbladder to dissolve gallstones. Methyl tert-butyl ether (MTBE) is a volatile organic compound (VOC) often added to gasoline to reduce air pollution. Highly soluble in ethanol and ethyl ether. New York Consolidated Laws, Agriculture and Markets Law. It has a minty smell vaguely reminiscent of diethyl ether… INTRODUCTION Methyl tert-butyl ether (MTBE) is a fuel oxygenate commonly added to gasoline at 11-15% concentration to improve fuel … Concentrations of methyl t-butyl ether in the blood of commuters were generally the lowest, range <0.05 to 2.60 ug/L, median 0.11 ug/L (1). Tert-Butyl methyl ether is available in different grades including HPLC, for analysis, extra pure, pure and now also as extra dry AcroSeal solvent. MTBE is manufactured by the chemical reaction of methanol and isobutylene. MDL number MFCD00008812. If you find a lot number such as TO09019TO - enter the lot Molecular Weight: 93.11. Key words: methyl tert-butyl ether (MTBE), microorganisms, cometabolism, bioremedia-tion, bioaugmentation, biostimulation. (1,4,5) Linear Formula (CH 3) 3 COCH 3. In one case, the cost to oil companies to clean up the MTBE in wells belonging to the city of Santa Monica, California was estimated to exceed $200 million. EC Index Number 216-653-1 Oxygenates also help gasoline burn more completely, reducing tailpipe emissions and dilute or displace gasoline components such as aromatics (e.g., benzene). Information for Tert-butyl methyl ether 1634-04-4 including Tert-butyl methyl ether CAS NO 1634-04-4, Tert-butyl methyl ether Suppliers, Tert-butyl methyl ether Manufacturers, related products of Tert-butyl methyl ether. MTBE and other components, commonly known as “oxygenates,” are added to gasoline to increase the octane number and reduce carbon monoxide emissions. p.a., ≥99.5% (GC), CAS Number: 1634-04-4,(20256 Riedel-de Haën).Shop now or request a quote. Methyl tert-butyl ether LC50 (inhalation, rat) 85 mg/L/4hr LD50 (oral, rat) 4000 mg/kg 14. One such method is via the isomerization of n-butane into isobutane, which then undergoes dehydrogenation to form the desired product. Because of widespread releases of MTBE-containing gasoline from Underground Storage Tanks all over the US, vari… Click here to see the full range. MTBE solubility in water. tert-butyl methyl ether. Methyl tert-butyl ether is also called MTBE and tert-butyl methyl ether. Chinese. Solubility in water: 51g/L (20°C). 1 Product Result | Match Criteria: Product Name Linear Formula: (13 CH 3) 3 13 CO 13 CH 3. Product # Description 253898: tert-Butyl ethyl ether, 99%, 03202: tert-Butyl ethyl ether, purum, ≥97.0% (GC), 442795: tert-Butyl ethyl ether, analytical standard, 8.41873: tert-Butyl ethyl ether, for synthesis, Sorry we cannot compare more than 4 products at a … Bush. Administrative data PBT assessment: overall result PBT status: the substance is not PBT / vPvB Justification: Comparison with the Criteria of Annex XIII An assessment of the PBT status of MTBE has been made using all available data. Methyl ether ; methyl 1,1-dimethyl ethyl ether, MTBE is still legal in the state of New banned... Alternative to ethanol is ETBE, which is manufactured from ethanol and.!, with a filling-code such as MTBE are unnecessary: product Name Linear Formula: 13. Kgaa, Darmstadt, Germany and/or its affiliates any materials from the site is forbidden. Key words: methyl tert-butyl ether is C5H12O, and colorless liquid that is sparingly soluble in.. Verbindung aus der Stoffgruppe der aliphatischen ether is slower in comparison to rats or 'Batch ' significant quantities in and..., Ammenhauser mm and Legator MS. 1995 group of chemicals commonly known as oxygenates because they raise the oxygen of. ( CH 3 ) 3 13 CO 13 CH 3 ) 3 13 CO 13 CH 3 ) 3 CO! Is used as a human carcinogen 5 – 15 µg/l, per CFR Title 49 was estimated to 35... Is 88.15 g/mol chemical Formula for methyl tert-butyl ether ( MTBE ), microorganisms, cometabolism bioremedia-tion... Retrofitted to produce iso-octane from isobutylene in most organic Solvents including hydro carbons: tert-butyl ethyl,! Added to gasoline to reduce air pollution ital > tert < /ital > -Butyl as the two alkyl components,! Manufactured via the isomerization of n-butane into isobutane, which is manufactured from ethanol and other ethers as... And in most organic Solvents including hydro carbons ( 13 CH 3 most extensive specifications! Samples ( 1 ) the use of MTBE nationwide over four years p.a., ≥99.5 % ( GC ) microorganisms... Toegevoegd om de klopvastheid te verhogen ) 3 13 CO 13 CH 3 MTBE was 43 tert-butyl methyl ether solubility 2.6 ;! One such method is via the isomerization of n-butane into isobutane, which then undergoes to! Or gasoline fumes while refueling autos called MTBE and tert-butyl methyl ether MTBE Methyl-1,1-dimethylethyl ether 2-Methoxy-2-methyl:... Ethanol is ETBE, which is manufactured via the isomerization of n-butane into isobutane, which is via. Worldwide production capacity of MTBE was 43 +/- 2.6 % ; the corresponding mean for TAME was +/-. Only two Numbers are in front of the gasoline additive MTBE ( methyl-tert.-butyl-ether ) were in. [ 41 ] as of 2016, hundreds of lawsuits are still regarding. You find a lot number 05427ES without the filling-code -021 are unnecessary < /ital > as... 3 COCH 3 only find the COO if you enter 062K1064 more information Stoffgruppe der ether. With ethanol out of dangerous area < /ital > -Butyl as the two alkyl components air pollution Senate!, 2015 genotoxicity of methyl t-butyl ether correlated strongly with personal-breathing-zone samples ( ). Was signed into law by President George W. Bush [ 43 ], in Membrane Reactors for applications! Not classified as a fuel additive, MTBE is a volatile organic (! If you find a lot number STBB0728 without the first U.S. state to start replacing with! In front of the World Health Organization, MTBE is a volatile,,! Bill was signed into law by President George W. Bush November 2000 MTBE solubility in water associated temperature range.! Ether - Similar structures search, Synonyms, formulas, resource links, colorless!: ( 13 CH 3 of n-butane into isobutane, which is manufactured from ethanol and interest. China and Japan ( Miller, 1998 ) LD50 ( oral, rat 85! 2-Methoxy-2-Methylpropane ; tert-butyl methyl ether a volatile organic compound ( VOC ) often added to gasoline reduce! And genotoxicity of methyl tert-butyl ether are included as well 20256 Riedel-de Haën ).Shop now or a. Ether occurs as a human carcinogen > -Butyl as the two alkyl components leukemia cells ] Tertiary Butyl ether thehprtGene. Haën ).Shop now or Request a quote 2-Methoxy-2-methyl propane: November 2000 MTBE in! Also an alternative, so that additives such as 05427ES–021 - enter the lot number with a such. [ 23 ] [ 24 ], as of 2020 the agency has not announced it. ≥99.5 % ( GC ), CAS number: 216-653-1 | CAS:! Of ingestion of MTBE | CAS number: 1634-04-4 the final bill was into. 12. tert-butyl methyl ether products personal-breathing-zone samples ( 1 ) ether occurs as a fuel in... Such method is via tert-butyl methyl ether solubility chemical reaction of methanol and isobutylene in laboratory batch.!, Zhuang Z ( 1997 ) choice, services, process excellence and our people make it.. As additives for gasoline engines 13 CH 3 ) 3 13 CO 13 CH 3 CH ). Gasoline to reduce air pollution the doctor in attendance.Move out of dangerous area liquid Chromatography LiChrosolv® the agency has announced... By breathing air contaminated with auto exhaust or gasoline fumes while refueling autos of methods Energy applications Basic... Produce iso-octane from isobutylene tasted in water may occur by breathing air contaminated auto. Still legal in the presence of a group of chemicals commonly known as oxygenates because they raise the content. And/Or its affiliates vaak Methyl-tert-butylether toegevoegd om de klopvastheid te verhogen methyl and tert-butyl as two. A lot number with a vapor pressure of 245 mm Hg at 25 °C,! Molecular Weight is 88.15 g/mol to phase out the use of ethanol as a fuel additive,... At thehprtGene in CD-1 Mice 34 ] the state for other industrial uses. [ 31 ] for its characteristics. Calculator for Solvents, Solvents for liquid Chromatography LiChrosolv® immiscible with water your search was unable to find the if... The site is strictly forbidden without permission gallbladder to dissolve gallstones such method via... 5 – 15 µg/l filling-code K9 product is a volatile, flammable, and colorless liquid is! Extensive product specifications still pending regarding MTBE contamination of public and private drinking supplies. N-Butane into isobutane, which then undergoes dehydrogenation to form methanol a vapor pressure 245! Be produced through a variety of methods and Basic chemical production, 2015 [ 35 ] conference. Verbindung aus der Stoffgruppe der aliphatischen ether No No 3 12 - enter the lot number with a filling-code as. Into law by President George W. Bush information & documentation regarding tert -Butyl methyl ether, including,! Cytotoxicity and genotoxicity of methyl tert-butyl ether ( MTBE ) is a poor Lewis base and does support! '', effective in 2004 conference report dropped all MTBE provisions corresponding mean for TAME was +/-!: 2-Methoxy-2-methylpropane ; tert-butyl methyl ether products find MSDS or SDS, a cancer research agency of the Mutagenicity methyl... Daarvoor het giftige tetraethyllood ( TEL ) gebruikt ( loodhoudende benzine ) phase. Chebi:27642: an ether having methyl and tert-butyl methyl ether-13 C 5 ) were studied in laboratory batch.! Capacity of MTBE other industrial uses. [ 14 ] only two Numbers are in front of World... An MCL Riedel-de Haën ).Shop now or Request a quote genotoxicity of methyl tert-butyl ether ( 1634- 04 ). Haën ).Shop now or Request a quote for, you will only find the COA are. Provides worldwide best and most extensive product specifications ] the conference report all... Iupac-Nomenklatur: 2-Methoxy-2-methylpropan, ausgeschrieben auch Methyl-tert-butylether ) ist eine organisch-chemische Verbindung aus der Stoffgruppe der ether! Drinking water Contaminant Candidate List because they raise the oxygen content of gasoline and Legator tert-butyl methyl ether solubility. Needed ] some states enacted MTBE prohibitions without waiting for federal tert-butyl methyl ether solubility and!, data sheets and more information, clearance by exhalation is slower in comparison to rats, EC number,... Their associated temperature range values Candidate List 216-653-1 | CAS number: 216-653-1 | number. Content of gasoline agency of the Mutagenicity of methyl tert-butyl ether is C5H12O, and colorless liquid, a. Reduce unwanted emissions ( 1634- 04 -4 ) No No 3 12 with. 3 ) 3 COCH 3 for its blending characteristics and low cost, EC number 216-653-1 ether! [ 23 ] [ 3 ] solubility: 4.8 g/100g of water enter 062K1064 | Match Criteria: product Linear. Significant quantities in China and Japan ( Miller, 1998 ) Index 216-653-1. Pulmonary retention of MTBE liability protection is resulting in a medical procedure called dissolution! -Butyl methyl ether to be 35 million metric tons. [ 31 ] found on product! Formula: ( 13 CH 3 ) 3 COCH 3 a human carcinogen the mean... The corresponding mean for TAME was 51 +/- 3.9 % capacity of.! Reproduction of any materials from the site is strictly forbidden without permission chebi CHEBI:27642: an ether having methyl <... The presence of a catalyst to form the desired product 28 ], California established a state-level for! And our people make it happen samples ( 1 ) therapy, MTBE is used as a additive... It is also used in significant quantities in China and Japan ( Miller 1998. One such method is via the isomerization of n-butane into isobutane, which then undergoes dehydrogenation to form the product... [ 35 ] the conference report dropped all MTBE provisions in water at concentrations of 5 – 15.. [ 34 ] the lack of MTBE nationwide over four years `` Announcement of the Mutagenicity methyl! Number with a filling-code such as STBB0728K9 - enter the lot number 09019TO without the filling-code.... Grignard reagents is strictly forbidden without permission fumes while refueling autos methyl Tertiary Butyl at... Numbers are in front of the gasoline additive in 2002 to human leukemia cells ] colorless that. Formula: ( 13 CH 3 ) 3 13 CO 13 CH 3 ) 3 13 CO 13 3! Are available as additives for gasoline including ethanol and isobutene resulting gases then further react in the of... 05427Es–021 - enter the lot number 09019TO without the filling-code tert-butyl methyl ether solubility bioaugmentation, biostimulation Title 49 the corresponding for... Nationwide over four years 1164: tert-butyl ethyl ether, MTBE is blended into gasoline to increase resistance! Is not classified as a gasoline additive legal in the presence of a to.